LEMAIRE RESEARCH GROUP
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54. Bonanno, N.M.; Sanz, C.; Patrick, B.O.; Lemaire, M. T. Synthesis and properties of 4-substituted phenols bearing 8-aminoquinoline substituents at 2,6 ring positions.  Manuscript in preparation, 2021.

53. Pelaccia, M.; Bonanno, N.M.; Jewel, S.; Sanz, C.; Patrick, B.O.; Lough, A.J.; Seda, T.; Lemaire, M.T.  Heteroleptic iron(III) complexes containing qsal or qsalCl and a redox-active arylazo ligand:  Syntheses, structures & magnetic properties.  Manuscript in preparation, 2021.

52. Bonanno, N.M.; Watts, Z.; Mauws, C.; Patrick, B.O.; Wiebe, C.R.; Shibano, Y.; Sugisaki, K.; Matsuoka, H.; Shiomi, D.; Sato, K.; Takui, T.; Lemaire, M.T. Valence tautomerism in a [2×2] Co4 grid complex containing a ditopic arylazo ligand​.  Chem. Commun., 2021, 57, 6213 - 6216.

51. Bonanno, N.M.; Lough, A.J.; Lemaire, M.T. Structural and magnetic properties of an ionic Zn5 cluster containing radical ligands.  Accepted for publication, Crystal Growth & Design, 2020, 20, 5709-5715.

50.  Bonanno, N.M.; Patrick, B.O.; Seda, T.;  Lemaire, M.T. A neutral Fe4tBuL4 all ferric grid complex:  Structural and variable temperature magnetic properties​.  Eur. J. Inorg. Chem. 2020, 711-715.

49.  Bonanno, N.M.; Lough, A.J.; Lemaire, M.T. A trinuclear nickel(II) cluster containing a ditopic redox active ligand:  Structural and magnetic properties​.  Polyhedron, 2020, 183, 114536.

48. Dale, S.; Bonanno, N.M.; Pelaccia, M.; Lough, A.J.; Miyawaki, A.; Takahashi, K.; Lemaire, M.T. Ligand mixed-valence and electrical conductivity in coordination complexes containing a redox-active phenalenol-substituted ligand.  Dalton Trans, 2019, 48, 8053 - 8056​.

47.  Bonanno, N.M.; Lough, A.J.; Lemaire, M.T. Polynuclear Cu4L4 copper(II)-aminyl radical coordination complexes.  Inorg. Chem. 2018​, ​57, 4837-4840.  

46.  Bonanno, N.M.; Poddutoori, P. K.; Sato, K.; Sugisaki, K.; Takui, T. Lough, A. J. and Lemaire, M.T. Reversible solution pi-dimerization and long multicenter bonding in a stable phenoxyl radical.  Chem. Eur. J. 2018​, 24, 14906-14910.

45. Bonanno, N.M.; Taylor, R.A; Cibian, M.; Yadav, J.; Silverstein, H.J.; Wiebe, C.R.; Mauws, C.; Lough, A.J.; Lemaire, M.T.  Homoleptic lanthanide complexes containing a redox-active ligand and the investigation of their electronic and photophysical properties.   Inorganics, 2018​, 6, 56-69.

44. Taylor, R.A.; Bonanno, N.M.; Mirza, D.; Lough, A.J.; Lemaire, M.T. A trivalent cobalt complex with the new redox-active ligand 10-(8-quinolylazo)-9-phenanthrol (qapl).  Polyhedron 2017, 131, 34-39.

43. Bonanno, N.M.; Lough, A.J.; Poddutoori, P.K.; Lemaire, M.T. Synthesis, characterization and copper(2+) coordination chemistry of a polytopic paramagnetic ligand.  Magnetochemistry 2017, 3, 15-23. 

42. Taylor, R.A; Lough, A.J.; Seda, T.; Poddutoori, P.K.; Lemaire, M.T. Di- and trivalent iron complexes with redox active 1-(2-pyridylazo)-2-phenanthrol (papl).  Polyhedron 2017, 123, 462-469.
 
41. Bonnano, N.M.; Walsby, C.; Prosser, K.; Lough, A.J.; Poddutoori, P.K.; Lemaire, M.T. A stable open-shell ditopic redox-active ligand.  Dalton Trans., 2016, 45, 5460-5463.
 
40. Taylor, R.A; Lough, A.J.; Lemaire, M.T. Spin-crossover in a homoleptic cobalt(II) complex containing a redox-active NNO ligand.  J. Mater. Chem. C, 2016, 4, 455-459.
 
39. Taylor, R.; Lough, A.J.; Lemaire, M.T Structural features and electronic properties of a cupric complex with redox active 1-(2-pyridylazo)-9-phenanthrol (papl).  Polyhedron 2016, 108, 74-79.
 
38. Bonanno, N.M.; Van Damme N.; Lough, A.J.; Lemaire, M.T. Transition metal complexes containing a ditopic redox active ligand featuring very intense visible absorption bands.  Dyes Pigm. 2015, 123, 212-217.
 
37. Sheepwash, M.A.L.; Lough, A.J.; Poggini, L.; Poneti, G.; Lemaire, M.T. Structure, magnetic properties and electronic structure of a nickel(II) complex with redox-active 6-(8-quinolylamino)-2,4-bis(tert-butyl)phenol. Polyhedron 2016, 108, 2-7.
 
36. Dinsdale, D.R.; Lough, A.J. ; Lemaire, M.T. Structure and magnetic properties of an unusual homoleptic iron(III) thiocyanate dimer.  Dalton Trans. 2015, 44, 11077-11082.
 
35. Dowling, C.; Dinsdale, D.R.; Lemaire, M.T. Preparation, electrochemical behavior and variable temperature magnetic properties of Co(3,5-DBSQ)2 complexes of imidazole- or pyrazole-substituted ligands.  Can. J. Chem. 2015, 93, 769-774.
 
34. Van Damme, N.; Zaliskyy, V.; Lough, A.J.; Lemaire, M.T. Structure and magnetic properties of a cobalt(III) complex with redox active 1-(2-pyridylazo)-2-phenanthrol (papl).  Polyhedron 2015, 89, 155-159.
 
33. Dowling, M.; Lemaire, M.T. Preparation, electrochemical behavior and variable temperature magnetic properties of transition metal complexes containing 2-phenyl-4,5-di-(2-pyridyl)imidazole.  Transit. Metal Chem. 2014, 39, 843-848.
 
32. Wilson, D.; Djukic, B.; Lemaire, M.T. Synthesis of bromine- or aryl-substituted ditopic Schiff base ligands and their bimetallic iron(II) complexes:  Electronic and magnetic properties.  Transit. Metal Chem. 2014, 39, 17-24.
 
31. Van Damme, N.; Lough, A.J.; Gorelsky, S.I.; Lemaire, M.T. Molecular and electronic structures of complexes containing 1-(2-pyridylazo)-2-phenanthrol (PAPL):  Revisiting a redox-active ligand.  Inorg. Chem. 2013, 52, 13021-13028. 
 
30. Djukic, B.; Jenkins, H.A.; Seda, T.; Lemaire, M.T. Structural and magnetic properties of homoleptic iron(III) complexes containing N-(8-quinolyl)-salicylaldimine [Fe(Qsal)2]+X- {X = I or (Qsal)FeCl3}. Transit. Metal Chem. 2013, 38, 207-212. 
 
29. Revunova, K.; Gorelsky, S.I.; Lemaire, M. T. Synthesis and coordination chemistry of a ditopic precursor to a triarylamminium radical cation ligand.  Polyhedron 2013, 52, 1118-1125.
 
28. Djukic, B.; Lough, A. J.; Seda, T.; Gorelsky, S. I. ; Lemaire, M.T. Pi-extended and six-coordinate iron(II) complexes:  Structures, magnetic properties, and the electrochemical synthesis of a conducting iron(II) metallopolymer.  Inorg. Chem. 2011, 50, 7334-7343.
 
27. Lemaire, M.T. Progress and design challenges for high-spin molecules. Pure and Appl. Chem., 2011, 83, 141-149. 
 
26. Adugna, S.; Revunova, K.; Djukic, B.; Gorelsky, S.I.; Jenkins, H.A.; Lemaire, M.T. Persistent metal bis(hexafluoroacetylacetonato) complexes featuring a 2,2-bipyridine substituted triarylamminium radical cation. Inorg. Chem. 2010, 49, 10183-10190. 
 
25. Cheng, H.; Djukic, B.; Jenkins, H.A.; Gorelsky, S.I.; Lemaire, M.T. Iron(II) complexes containing thiophene-substituted “bispicen” ligands:  Spin-crossover, ligand rearrangements, and ferromagnetic interactions. Can. J. Chem. 2010, 88, 954-963. 
 
24. Djukic, B; Singh, M.A.; Lemaire, M.T. Formation of Spin-Crossover Polymer Microspheres. Syn. Metals 2010, 160, 825-828. 
 
23. Djukic, B.; Lemaire, M.T. A Hybrid Spin-Crossover Conductor Exhibiting Unusual Variable Temperature Electrical Conductivity.  Inorg. Chem. 2009, 48, 10489-10491.
 
22. Djukic, B.; Poddutoori, P.K.; Dube, P.A.; Seda, T.; Jenkins, H.A.; Lemaire, M.T. Bimetallic iron(3+) spin-crossover complexes containing a 2,2’-bithienyl bridging bis-QsalH ligand. Inorg. Chem. 2009, 48, 6109-6166. 
 
21. O’Sullivan, T.J.; Djukic, B.; Dube, P.A.; Lemaire, M.T. Preparation and properties of thienyl and 2,2’-bithienyl substituted cobalt-bis(semiquinone) valence tautomers.  Can. J. Chem. 2009, 87, 533-538. 
 
20. O’Sullivan, T.J.; Djukic, B.; Dube, P.A.; Lemaire, M.T. A Conducting Metallopolymer Featuring Valence Tautomerism. Chem. Commun. 2009, 1903-1905. 
 
19. Djukic, B.; Dube, P.A.; Razavi, F.; Seda, T.; Jenkins, H.A.; Britten, J. F.;   Lemaire, M.T. Preparation and magnetic properties of iron(3+) spin-crossover complexes bearing a thiophene substituent:  Toward multifunctional metallopolymers.  Inorg. Chem. 2009, 48, 699-707. 
 
18. Cheng, H.; Djukic, B.; Harrington, L.E.; Britten, J.F.; Lemaire, M.T. N'-(3-Thienylmethylene)pyridine-2-carbohydrazide. Acta Cryst. E. 2008, E64, o719. 
 
17. Djukic, B.; Harrington, L.E.; Britten, J.F.; Lemaire, M.T. 5,7-Di-2-pyridyl-2,3-dihydrothieno[3,4-b][1,4]dioxine.  Acta Cryst. E. 2008, E64, o463.  
 
16. Lemaire, M.T. Recent developments in the coordination chemistry of stable free radicals. Pure Appl. Chem. 2004, 76, 277–293.
 
15. Gilroy, J.B.; Lemaire, M.T.; Patrick, B.O.; Hicks, R.G. Structure and magnetism of a verdazyl radical clathrate hydrate. Strong intermolecular magnetic interactions derived from -stacking within ice-like channels. CrystEngComm. 2009, 11, 2180-2184.
 
14. Lemaire, M.T.; Barclay, T.M.; Thompson, L.K.; Hicks, R.G.  Synthesis, structure, and magnetism of a binuclear cobalt(II) complex of a potentially bis-tridentate verdazyl radical ligand.  Inorg. Chim. Acta. 2006, 359, 2616 – 2621.
 
13. Koivisto, B.D.; Ichimura, A.S.; McDonald, R.; Lemaire, M.T.; Thompson, L.K.; Hicks, R. G.  Intramolecular -Dimerization in a 1,1'-Bis(verdazyl)ferrocene Diradical.  J. Am. Chem. Soc. 2006, 128, 690 – 691.
 
12. Shuaev, K.V.; Rawson, J.M.; Passmore, J.; Cameron, T. S.; Thompson, L.K.; Lemaire, M.T.  Preparation and Solid State Characterization of the Novel Mixed Biradical NSNSC-CNSSN.  Inorg. Chem. 2005, 44, 2576.
 
11. Thompson, L.K.; Kelly, T.L.; Dawe, L.N.; Grove, H.; Lemaire, M.T.; Howard, J.A.K.; Spencer, E.C.; Matthews, C.J.; Onions, S.T.; Coles, S.J.; Horton, P.N.; Hursthouse, M. B.; Light, M.E.  Mixed Valence Mn(II)/Mn(III) [3×3] Grid Complexes: Structural, Electrochemical, Spectroscopic, and Magnetic Properties. Inorg. Chem.  2004, 43, 7605. 
 
10. Hicks, R.G.; Koivisto, B.D.; Lemaire, M.T.  Synthesis of Multitopic Verdazyl Radical Ligands. Paramagnetic Supramolecular Synthons.  Org. Lett. 2004, 6, 1887.    
 
9. Barclay, T.M.; Hicks, R.G.; Lemaire, M.T.; Thompson, L.K.  Verdazyl Radicals as Oligopyridine Mimics:  Structures and Magnetic Properties of M(II) Complexes of 1,5-Dimethyl-3-(2,2´-bipyridin-6-yl)-6-oxoverdazyl (M = Mn, Ni, Cu, Zn).  Inorg. Chem. 2003, 42, 2261.
 
8. Barclay, T.M.; Hicks, R.G.; Lemaire, M. T.; Thompson, L.K.; Xu, Z.  Synthesis and Coordination Chemistry of a Water-Soluble Verdazyl Radical.  Structures and Magnetic Properties of M(H2O)2(vdCO2)2·2H2O [M = Co, Ni; vdCO2 = 1,5-dimethyl-6-oxo-verdazyl-3-carboxylate].  Chem. Commun. 2002, 1688.
 
7. Barclay, T.M.; Hicks, R.G., Lemaire, M.T.; Thompson, L.K.  Weak Magnetic Coupling of Coordinated Verdazyl Radicals Through Diamagnetic Metal Ions.  Synthesis, Structure, and Magnetism of a Homoleptic Copper(I) Complex.  Inorg. Chem. 2001, 40, 6521.
 
6. Barclay, T.M.; Hicks, R.G.; Lemaire, M.T.; Thompson, L.K.  Synthesis, Structure, and Magnetism of Bimetallic Manganese or Nickel Complexes of a Bridging Verdazyl Radical.  Inorg. Chem. 2001, 40, 5581.
 
5. Hicks, R.G.; Lemaire, M.T.; Öhrström, L.; Richardson, J.F.; Thompson, L.K.; Xu, Z.  Strong Supramolecular-Based Magnetic Exchange in -Stacked Radicals:  Structure and Magnetism of a Hydrogen-Bonded Verdazyl:Hydroquinone Molecular Solid. J. Am. Chem. Soc. 2001, 123, 7154.
 
4. Barclay, T.M.; Hicks, R.G.; Lemaire, M.T.; Thompson, L.K.  Structure and Magnetic Properties of a Nickel(II) Complex of a Tridentate Verdazyl Radical:  Strong Ferromagnetic Metal-Radical Exchange Coupling.  Chem. Commun.  2000, 2141.
 
3. Hicks, R.G.; Lemaire, M.T.; Thompson, L.K.; Barclay, T.M.  Strong Ferromagnetic and Antiferromagnetic Exchange Coupling Between Transition Metals and Coordinated Verdazyl Radicals.  J. Am. Chem. Soc. 2000, 122, 8077.
 
2. Letkeman, P.; Lemaire, M.T.; Murase, I.; Motekaitis, R.J.; Martell, A.E. A Potentiometric study of metal chelates with pentaethylenehexaamineoctaacetic acid.  J. Coord. Chem. 2000, 52, 33.
 
1. Barr, C.L.; Chase, P.A.; Hicks, R.G.; Lemaire, M.T.; Stevens, C.L.  Synthesis and Characterization of Verdazyl Radicals Bearing Pyridine or Pyrimidine Substituents:  A New Family of Chelating Spin-Bearing Ligands.  J. Org. Chem. 1999, 64, 8893.

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